树脂吸附法处理水杨酸甲酯生产废水的研究

采用吸附树脂NDA—99处理水杨酸甲酯生产废水，结果表明该树脂时废水中的5磺基水杨酸及水杨酸均具有良好的吸附—脱附性能．废水经预处理和吸附处理后，CODCr由57000-59000mg／L降至6300mg／L左右，去除率接近89％．用IBV8％NaOH 3BVH2O作脱附剂，在温度为60℃、流量为IBV／h的条件下，脱附率接近100％，树脂可重复使用．高浓度脱附液经酸化、浓缩、冷却结晶，可回收5—磺基水杨酸，回收率为95％左右。纯度为78％。     

Preparation of Micron-size Functional Fluorescent Microspheres

As a kind of special functional microspheres, fluorescent polymer microspheres could be used in cell label and separation, blood flow assay, flow cytometer marking, chemical reaction assay,and in analyst of the transform and diffusion of particles in soil 1. However, one of the most important applications of fluorescent microspheres is in the high-throughput screening of drugs (HTS) 2. Through affinity interaction, radioactive ligands (latent drugs) are bound to fluorescent microspheres covered by receptor, and luminescence is produced by radioactivity, so ligands can be assayed and screened.In this study, we developed a technique for preparing micron-size fluorescent microspheres with different functional groups. The methods included the synthesis of micron-size polystyrene microspheres through the dispersion polymerization of styrene in different media such as ethanol,ethanol-water, and isopropanol; the functional polystyrene microspheres were prepared by introduction of functional monomers into the reaction system of styrene; the functional fluorescent microspheres were obtained by the way of dying functional microspheres in the fluorescent material's ethanol solvent.The average diameter of microspheres was in the range of 1～10 μm, and the distribution was normal distribution. The functional groups included -OH, -CHO, -COOH, -CONH2, and SO3H. The absorbing spectrum and exciting spectrum were tested, the results showed that the maximal absorbance of fluorescent microsphere was near 306.5 nm, and its maximal excitation was near 362 nm. The excitation spectrum of fluorescent material (DPO) and fluorescent microspheres were shown in figure 1, and it indicated that the developed fluorescent microspheres showed the same excitation behavior like DPO, which related to the fluorescent microspheres had stable luminescence property.     

TiO2光催化反应及其在环境保护中的应用

本文简要介绍了TiO2光催化剂的作用机理，讨论了影响TiO2光催化效率的因素及解决途径，综述了光催化在环境保护中的最新应用。     

快速响应的温敏性聚(N-异丙基丙烯酰胺)水凝胶 Ⅰ.以CaCO_3为成孔剂制备方法、表征及动力学研究

以不同粒径的CaCO3粒子为成孔剂 ,合成了快速响应的温敏性聚 (N 异丙基丙烯酰胺 ) (PNIPA)水凝胶 .利用扫描电镜观察到水凝胶具有特殊的孔状结构 ,得到水凝胶的孔径大小为几十微米左右 .动力学研究表明 ,该水凝胶在温敏膨胀或收缩时 ,具有快速的响应速率 ,在 10min内的失水率可达 90 % .比较了干凝胶和4 0℃下失水后的凝胶两种不同状态下水凝胶的膨胀曲线 ,发现两者的溶胀动力学曲线明显不同 ,前者的曲线有拐点 .同时发现与失水收缩速率相比 ,水凝胶具有较慢的吸水膨胀速率 .     

Synthesis and Structure Characterization of a Tetranuclear Manganese(Ⅲ) Complex:[Mn4O2(O2CMe)6(MeOH)2(dbm)2]·2MeCOOH·2CH2Cl2

The title compound, [Mn4O2(O2CMe)6(MeOH)2(dbm)2]·2MeCOOH·2CH2Cl2 (Hdbm = dibenzoylmethane), has been synthesized and structurally determined by single-crystal X-ray diffraction. The crystal belongs to triclinic, space group P(-l), with a = 10.729(3), b = 12.269(3), c =13.085(4) (A), a = 106.367(3), β = 107.643(2), γ = 94.771(2)°, V = 1547.9(7) (A)3, Z = 1,C50H64Cl4Mn4O24, Mr= 1410.57, Dc= 1.513 g/em3, F(000) = 724, Rint = 0.0147, T = 293(2) K and μ = 1.046 mm-1. The fimal R = 0.0359 and wR = 0.0938 for 5791 observed reflections with I ＞ 2( )I).The structure of the complex consists of one [Mn4(μ3-O)2]8+ core with four coplanar Mn atoms disposed in an extended "butterfly-like" arrangement and two O atoms triply bridging each "wing",and the peripheral ligation is provided by six μ2-MeCO2-, two terminalμ2-dbm- groups at the two hydrogen bonding interactions are found within the structure of the compound.     

吴茱萸次碱的合成进展

系统地总结了吴茱萸次碱的合成方法. 根据构建环的种类不同, 把合成方法分为七类, 大部分方法都是以色胺和邻氨基苯甲酸或其衍生物为起始原料, 步骤较长, 适合工业生产的简便、经济适用的方法还有待于进一步研究探索.     

Analysis of Chlorogenic Acid in Herbal Medicines by Capillary Electrophoresis

Atpresent,thecommonlyusedmethodforanalyzingherbalmedicinesishighperformanceliquidchromatography(HPLC).However,theuseofHPLCisrestrictedformanyreasons.Themostseriousproblemisthatthechromatographiccolumniseasilycontaminated.ComparedwithHPLC,capillaryelectrophoresis(CE)ischaracterizedwithhighefficiency,rapidity,lowcostandmultiplemodestobechosen.Inaddition,thecapillarycanbeeasilyregenerated.SoCEisidealforanalyzing"dirty"samples,suchasChineseherbalmedicines.Infact,studiesintheareaarebecoming…     

胺、醇、醚类化合物电离能的自相关拓扑研究

原子的染色序数 fi 定义为 :fi=gi·xi,式中 gi 为原子i在分子中的序数 ,xi 为其染色系数 .基于fi 建立改进的原子序数自相关拓扑指数mF ,其中的1F对烷烃及其衍生物具有良好的结构选择性 .使用第一电离能 (Ip)与0 F ,1F的数量关系模型对 32种脂肪族胺、醇、醚进行估算、预测 ,结果令人满意     

螯合树脂浓缩柱预富集低压离子色谱分光光度法测定海水中痕量铅

采用螯合树脂浓缩柱预富集低压离子色谱分光光度法测定海水中痕量的铅。对于2.0μg/L的Pb2 溶液,测定的相对标准偏差为2.9%(n=8);将该法应用于不同盐度海水中铅的测定,获得满意结果,标准加标回收率在94%~101%之间,该法可以识别Ⅰ类海水,可以测定Ⅱ~Ⅳ类海水。